Red Oxide

Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturally as the mineral magnetite. As the mineral known as hematite, Fe2O3 is the main source of iron for the steel industry. Fe2O3 is readily attacked by acids. Iron(III) oxide is often called rust, and to some extent this label is useful, because rust shares several properties and has a similar composition; however, in chemistry, rust is considered an ill-defined material, described as Hydrous ferric oxide.

Category:

Application

It is used for colour washes, distemper and oil paints. It is also used in making coloured paper. Red oxide pigments are widely used as primers for painting structural steel, automobile bodies, ship bottoms, etc.

Chemical formula

Fe2O3

Molar mass

159.687 g·mol−1

Appearance

Red solid

Odor

Odorless

Density

5.25 g/cm3

Melting point

1,539 °C (2,802 °F; 1,812 K)[1]
decomposes
105 °C (221 °F; 378 K)
β-dihydrate, decomposes
150 °C (302 °F; 423 K)
β-monohydrate, decomposes
50 °C (122 °F; 323 K)
α-dihydrate, decomposes
92 °C (198 °F; 365 K)
α-monohydrate, decomposes

Solubility in water

Insoluble

Solubility

Soluble in diluted acids,[1] barely soluble in sugar solution[2]
Trihydrate slightly soluble in aq. tartaric acid, citric acid, CH3COOH

Magnetic susceptibility (χ)

+3586.0×10−6 cm3/mol

Refractive index (nD)

n1 = 2.91, n2 = 3.19 (α, hematite)[

Crystal structure

Rhombohedral, hR30 (α-form)[5]
Cubic bixbyite, cI80 (β-form)
Cubic spinel (γ-form)
Orthorhombic (ε-form)[

Space group

R3c, No. 161 (α-form)[5]
Ia3, No. 206 (β-form)
Pna21, No. 33 (ε-form)[

Point group

3m (α-form)[5]
2/m 3 (β-form)
mm2 (ε-form)

Coordination geometry

Octahedral (Fe3+, α-form, β-form)[

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